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Yes, it is generally safe to take these two together daily

You should avoid wearing makeup or applying skincare or other potential sources of bacteria to your face for the first 24 hours after microneedling

1994 Mar 1;139(5):453-65

Pro-oxidant effects of flavonoids generally occur at high doses [303]

Most patients receive one intramuscular dose every three to four weeks, though the schedule may be shortened or extended based on symptom control and estradiol blood levels